AlphaDelta
AlphaDelta, the online tool to compute isotope fractionation for light stable isotopes (H, C, O, S)
AlphaDelta is an online tool and iOS app to compute the isotope fractionation for light stable isotopes (H, C, O, S). You can either compute the 1000 ln (alpha) value for a temperature or compute the temperature of equilibrium from the Delta value between two isotopic substances. More than 1100 equilibrium fractionation equations are compiled. The iOS app is available on the iTunes App store for FREE:
http://itunes.apple.com/ca/app/alphadelta/id421377528?mt=8
AlphaDelta is now rewritten in Swift with iOs, PadOS and MacOS apps -Here to download: http://itunes.apple.com/ca/app/id421377528?mt=8
NEW! AlphaDelta Android app can now be downloaded here:
https://play.google.com/store/apps/details?id=ca.ulaval.AlphaDelta.alpha_delta
Just added to AlphaDelta:
H2O(l)-H2(g) and H2O(l)-CH4(g) form
Horibe Y, Craig H (1995) D/H fractionation in the system methane-hydrogen-water. Geochimica et Cosmochimica Acta 59:5209-5217.
Just added to AlphaDelta, the theoretical sulfur isotope fractions for the sulfide-sulphate system from:
Eldridge DL, Guo W, Farquhar J (2016) Theoretical estimates of equilibrium sulfur isotope effects in aqueous sulfur systems: Highlighting the role of isomers in the sulfite and sulfoxylate systems. Geochimica et Cosmochimica Acta 195:171-200. doi: http://dx.doi.org/10.1016/j.gca.2016.09.021.
Just added to AlphaDelta the equations from :
-Chacko T, Deines P (2008) Theoretical calculation of oxygen isotope fractionation factors in carbonate systems. Geochimica et Cosmochimica Acta 72:3642-3660.
&
-van Dijk J, Fernandez A, Müller IA, Lever M, Bernasconi SM (2018) Oxygen isotope fractionation in the siderite-water system between 8.5 and 62 °C. Geochimica et Cosmochimica Acta 220:535-551. doi: https://doi.org/10.1016/j.gca.2017.10.009.
AlphaDelta updated with new equations:
Pollington AD, Kozdon R, Anovitz LM, Georg RB, Spicuzza MJ, Valley JW (2016) Experimental calibration of silicon and oxygen isotope fractionations between quartz and water at 250 °C by in situ microanalysis of experimental products and application to zoned low δ30Si quartz overgrowths. Chemical Geology 421:127-142.
Fernandez A, van Dijk J, Müller IA, Bernasconi SM (2016) Siderite acid fractionation factors for sealed and open vessel digestions at 70 °C and 100 °C. Chemical Geology 444:180-186. doi: http://dx.doi.org/10.1016/j.chemgeo.2016.10.015.
In addition, the S-isotope fractionations of Sakai (1968) have been recalculated by fitting theoretical data to ln 1000 alpha = a *10^6/T^2+b*10^3/T+c using the lm function of R software.
Siderite acid fractionation factors for sealed and open vessel digestions at 70°C and 100°C The oxygen isotope composition of siderites can be used to deduce the paleoenvironmental conditions under which the mineral formed. However, it is not clear whether the published fractionation factors (αCO2-siderite) for the acid digestion of siderites are appropriate for modern “on-line” sample pre...
AlphaDelta updated today with new equations:
Golyshev SI, Padalko NL, Pechekin SA (1981) Fractionation of stable oxygen and carbon isotopes in carbonate systems. Geochemistry International 18: 85-99.
Carbon isotope fractionations recalculated by fitting a polynominal 1000/T equation (lm function, R software) on 1000 ln B (mineral) - 1000 ln B (CO2).
AlphaDelta updated today with a new equation:
Saccocia PJ, Seewald JS, Shanks Iii WC (2015) Oxygen isotope fractionation in the portlandite–water and brucite–water systems from 125 to 450 °C, 50 MPa. Geochimica et Cosmochimica Acta 169: 137-151.
AlphaDelta updated today with a new equation:
Dalou C, Le Losq C, Mysen BO (2015) In situ study of the fractionation of hydrogen isotopes between aluminosilicate melts and coexisting aqueous fluids at high pressure and high temperature – Implications for the δD in magmatic processes. Earth and Planetary Science Letters 426: 158-166.
AlphaDelta has a new web address!
www2.ggl.ulaval.ca/cgi-bin/alphadelta/alphadelta.cgi
New: computing 1000 ln "alpha" returns a graph vs 10^6/T^2.
04/26/2014
AlphaDelta a une nouvelle adresse web!
www2.ggl.ulaval.ca/cgi-bin/alphadelta/alphadelta.cgi
Nouveauté: le calcul de 1000 ln "alpha" produit un graphique en fonction de 10^6/T^2.
AlphaDelta AlphaDelta offre deux possibilités de calcul : 1) calcul du fractionnement isotopique (1000 ln α) à une température donnée (nouveau-avec graphique);2) calcul de la température d'équilibre isotopique pour une différence de composition (Δ). 1) compute the isotope fractionation (1000 ln α) for a given…
08/17/2012
A new version of AlphaDelta is now available on the iTunes Store.
What is NEW!
1) A function to export a .csv formatted file of your last computations and send it by email.
2) A history of your computations, can be managed, deleted.
3) Cool: the new version optimized for the iPad! check it now!
Go to http://itunes.apple.com/ca/app/alphadelta/id421377528?mt=8
or update your app to get the new functionalities!!
Have fun! isotopes are cooooool!
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Université Laval
Quebec, QC